PCB Printed Wiring Board - A Brief History:
The
first PCB patents for "printed wire" were issued in the early 1900's
but PCBs that we would recognize first came into use after World War II. In
1925, Charles Ducas of the United States submitted a patent application for a
method of creating an electrical path directly on an insulated surface by
printing through a stencil with electrically conductive inks. Hence the name
"printed wiring" or "printed circuit." An Austrian
scientist, Dr Paul Eisler, is credited with making the first operational
printed wiring board in 1943. It was used as a replacement for bulky radio tube
wiring.
PCB – Used in the 1920's 
The
earliest PCB's (printed circuit boards) were made from materials like Bakelite,
Masonite, layered cardboard and even thin wooden planks. Holes were drilled
into the material and then flat brass "wires" were riveted or bolted
onto the board. Connections to components were usually made by pressing the end
of the brass trace onto a hollow rivet and the component's leads were simply
pressed into the open end of the rivet. Occasionally small nuts and bolts were
used in place of the rivets. These types of PCBs were used in early tube style
radios and gramophones in the 1920's. By the 50's and early 60's laminates
using different types of resins mixed with all sorts of different materials
were being introduced but the pcbs were still single sided. The circuitry was
on one side of the board and the components on the other. The advantages of the
PCB over bulky wiring and cables made it a prime choice for new products being
brought into the market place. But the largest influence on the evolution of
the printed wiring board came from the government agencies responsible for new weapons
and communication equipment. Wire ended components were being used in some of
the applications. In the beginning the leads of the components were held in
place on the board by using small nickel plates welded to the lead after it was
placed through the hole. 
PCB - The Evolution of the Production Process 
Eventually
processes were developed that would plate copper onto the walls of the drilled
holes. That allowed circuits on both sides of the board to be connected
electrically. Copper had replaced brass as the metal of choice because of its
ability to carry electrical current, relatively low cost and ease of
manufacturing. In 1956 the US Patent Office issued a patent for the
"Process of Assembling Electrical Circuits" that was sought by a
small group of scientists represented by the US Army. The patented process
involved using a base material like melamine to which a layer of copper foil has
been securely laminated. A drawing was made of the wiring pattern and then photographed
onto a zinc plate. The plate was used to create a printing plate for an offset
printing press. An acid resistant ink was printed onto the copper foil side of
the board that was etched to remove the exposed copper leaving the
"printed wire" behind. Other methods like using stencils, screening,
hand printing and rubber stamping were also proposed to deposit the ink
pattern. Holes were then punched in patterns using dies to match the position
of the component wire leads or terminals. The leads were inserted through the
non-plated holes in the laminate material and then the card was dipped or
floated on a bath of molten solder. The solder would coat the traces as well connecting
the leads of the components to the traces. They also used tinned eyelets,
rivets and washers to attach various types of components to the board. Their
patent even has a drawing showing two single sided boards stacked on top of
each other with a standoff holding them apart. There are components on the top
side of each board and one component shown with its leads extending through the
top board into holes on the bottom board, connecting them together, a rough
attempt at making the first multi-layer. Much has changed since then. With the
advent of plating processes that allowed hole walls to be plated came the first
double sided boards. Surface mount pad technology, something we associate with
the 1980's was actually being explored twenty years earlier in the 60's. Solder
masks were being applied as early as 1950 to help reduce the corrosion that was
occurring to traces and components. Epoxy compounds were spread over the
surface of the assembled boards similar to what we know now as conformal
coating. Eventually the inks were being screen printed onto the panels before
assembling the boards. Areas that were meant to be soldered were blocked out on
the screens. It helped keep the boards clean, reduce corrosion and oxidation
but the tin/lead coating used to coat the traces would melt during the
soldering process causing the mask to flake off. Because of the wide spacing of
the traces it was seen more as a cosmetic problem than a functional issue. By
the 1970's circuitry and spacing was becoming smaller and smaller and the
tin/lead coating that was still being used to coat the traces on the boards
began fusing traces together during the soldering process. Hot air soldering
methods began in the late 70's allowing the tin/lead to be stripped after etching
eliminating the problem. Solder mask could then be applied over the bare copper
circuits and leave only the plated holes and pads free to be coated with
solder. As holes continued to get smaller and trace work became more densely
packed solder mask bleed and registration issues brought on dry film masks.
They were primarily used in the US while the first photo-imageable masks were
being developed in Europe and Japan. In Europe the solvent based
"Probimer" ink was applied by curtain coating the entire panel. The
Japanese centered on screen processes using various aqueous developed LPIs. All
of three of these mask types used standard UV exposure units and photo tools to
define the pattern on the panel. By the mid 1990's the aqueous developed etching
eliminating the problem. Solder mask could then be applied over the bare copper
circuits and leave only the plated holes and pads free to be coated with
solder. As holes continued to get smaller and trace work became more densely
packed solder mask bleed and registration issues brought on dry film masks.
They were primarily used in the US while the first photo-imageable masks were being
developed in Europe and Japan. In Europe the solvent based "Probimer"
ink was applied by curtain coating the entire panel. The Japanese centered on
screen processes using various aqueous developed LPIs. All of three of these
mask types used standard UV exposure units and photo tools to define the
pattern on the panel. By the mid 1990's the aqueous developed
Why is Solder Mask Green for PCB's? 
Ever
wonder why the solder mask on almost every circuit board made is green? Well
there seems to be any number of unsubstantiated reasons. Everything from the
involvement of the US government in developing and using the first circuit
boards to the how easy it was on your eyes during the long hours of hand
assembling the first boards. Here's the most believable explanation I've heard.
The original masks used a base resin that was a "brownish yellow" and
a hardener that was a deeper muddy brown. When they were mixed together they
created a honey brown color that apparently not very appetizing. They tried adding
red pigments but it became a rusty adobe color and using blue simply made it a
darker brown. None of them were very appealing colors. Since the laminate
materials at the time had a green hue they tried adding more yellow and some
blue and ended up with an acceptable green color. It became the standard color
we are still using today.
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